Chemical cages could store hydrogen, expand use of clean-burning fuel

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https://www.science.org/content/article/chemical-cages-could-store-hydrogen-expand-use-clean-burning-fuel

By ROBERT F. SERVICE, Science. 

Excerpt: Cheap molecular “sponges” made with aluminum can be low-pressure gas tanks. Hydrogen seems like the perfect fuel. By weight it packs more punch than any other fuel. It can be made from water, meaning supply is almost limitless, in principle. And when burned or run through a fuel cell, it generates energy without any carbon pollution. But hydrogen takes up enormous volume, making it impractical to store. Compressing it helps, but is expensive and essentially turns hydrogen storage tanks into high-pressure explosives. Now, a molecular sponge made of organic compounds and cheap aluminum promises a practical solution, holding significant amounts of hydrogen at low pressures. Described in a paper accepted last week at the Journal of the American Chemical Society (JACS), it is the latest in a series of promising metal-organic frameworks (MOFs), and it suggests that the materials could be close to a mass market application, serving as fuel depots for backup power sources at industrial operations....

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